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If this guide fails you: Click Here, then follow the steps below.
I followed every Desynch Guide on the Internet and I still desynch. ANTHER HELP!
You most likely have a conflicting setting in dolphin somewhere so to ease things up, you will need to go into your Documents Directory, locate your "Dolphin Emulator" folder. You will need to either delete it, or rename the folder. When you start up dolphin again, it will recreate that directory. When you're done, you will have to follow the above guide to fix all your settings. For mac users: to find this directory: Click Here: